An advanced one-dimensional, isothermal mathematical model for a single cel
l of an alkaline fuel cell (AFC) is presented. Advances in an expression fo
r the volume average velocity and in correlations and parameters are achiev
ed. The parameters and operating conditions of the model are based on the O
biter Fuel Cell, which is employed as a power source for NASA space shuttle
s. A stimulated result is obtained that shows a close agreement with some o
f the experimental data. Profiles of variables, local overpotential and loc
al current density are also obtained as a function of cell voltage. An inve
stigation of the influence of initial electrolyte concentration shows that
the performance of the AFC is maximized at a concentration of 3.5 M. Finall
y, it is found that increasing the operating pressure steadily enhances cel
l performance. (C) 1999 Elsevier Science S.A. All rights reserved.