Gallium liquid metal ion sources (LMISs) have been exposed to common gas an
d liquid phase laboratory and vacuum system contaminants. Minor changes in
the direct current and pulsed operation of the LMISs were observed after co
ntaminant exposure. Time-of-flight mass analysis of the ion emission reveal
ed that contaminant species are primarily field evaporated with the gallium
substrate. Low vapor pressure contaminants have been observed to constitut
e a significant portion of the total emitted ion current. (C) 1999 American
Vacuum Society. [S0734-211X(99)03206-0].