We demonstrate the use of a novel design of fibre-optical sensor (or 'local
probe') for immiscible-fluid discrimination in multi-phase flows. These pr
obes are made from standard silica fibres with plane oblique facets polishe
d at the fibre tip, with various surface treatments, including a crucial on
e for wettability control. Total internal reflection is used to distinguish
drops, bubbles or other regions of fluid in multi-phase flows, on the basi
s of refractive-index contrast. Such probes have quasi-binary outputs; we d
emonstrate in this paper their use in distinguishing water from oil (kerose
ne) in oil/water two-phase flows and compare the results with those obtaine
d from a simple cleaved fibre relying on the (small) difference in Fresnel
reflectivity for discrimination. Quantitative accuracy is demonstrated by c
omparison of profiles, across a pipe diameter, of local, time-averaged volu
me fractions ('hold-ups'), with pipe-averaged hold-ups determined from a ca
refully calibrated gradio-manometer in a fully developed region of the flow
. Companion papers deal with the sensors used and results achieved in gas/l
iquid flows and three-phase flows.