Synthesis, photophysics, and electrochemistry of dinuclear cadmium(II) diimine complexes with bridging chalcogenolate ligands. X-Ray crystal structures of [(phen)(2)Cd(mu-SC6H4CH3-p)](2)(PF6)(2) and [(phen)(2)Cd(mu-SeC6H5)](2)(PF6)(2)

Authors
Yam, VWW Pui, YL Cheung, KK
Citation
Vww. Yam et al., Synthesis, photophysics, and electrochemistry of dinuclear cadmium(II) diimine complexes with bridging chalcogenolate ligands. X-Ray crystal structures of [(phen)(2)Cd(mu-SC6H4CH3-p)](2)(PF6)(2) and [(phen)(2)Cd(mu-SeC6H5)](2)(PF6)(2), NEW J CHEM, 23(12), 1999, pp. 1163-1169
Citations number
68
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
12
Year of publication
1999
Pages
1163 - 1169
Database
ISI
SICI code
1144-0546(199912)23:12<1163:SPAEOD>2.0.ZU;2-N
Abstract
A new series of luminescent dinuclear six-coordinate cadmium(II) diimine co mplexes with bridging chalcogenolate ligands has been synthesized and chara cterized, and shown to exhibit interesting photophysical and electrochemica l properties. The X-ray crystal structures of [(phen)(2)Cd(mu-SC6H4CH3-p)]( 2)(PF6)(2) (11) and [(phen)(2)Cd(mu-SeC6H5)](2)(PF6)(2) (12) have been dete rmined.