Polymers containing backbone fluorescein, phenolphthalein and benzaurin. Synthesis and optical properties

Citation
Er. Silcoff et T. Sheradsky, Polymers containing backbone fluorescein, phenolphthalein and benzaurin. Synthesis and optical properties, NEW J CHEM, 23(12), 1999, pp. 1187-1192
Citations number
42
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
12
Year of publication
1999
Pages
1187 - 1192
Database
ISI
SICI code
1144-0546(199912)23:12<1187:PCBFPA>2.0.ZU;2-M
Abstract
In order to utilize the prominent fluorescence ability of fluorescein in li ght emitting devices, we have synthesized a series of polymers that contain fluorescein in their backbones. The key step of the synthesis, in which th e fluorescein unit and the polymer are created simultaneously, is the react ion of bis(2,4-dihydroxyphenyl)alkanes with phthalic anhydride. This new me thodology was also used for the synthesis of polymers containing phenolphth alein and benzaurin. All the new polymers completely maintained the optical and chemical characteristics of the parent pigment.