The energy loss of Net ions with keV energies scattered under grazing incid
ence from a LiF(001) surface is studied with a time-of-flight technique. Si
nce charge exchange in font of the wide-band-gap insulator is widely suppre
ssed, the energy loss of slow ions moving in front of the solid can be inve
stigated under specific interaction conditions. From the theoretical analys
is of data we find evidence for an energy loss mechanism based on the excit
ations of optical phonons in the insulator.