Structure of the gas-phase sp- and d-element bis(dipivaloylmethanato) complexes

Authors
Girichev, GV Giricheva, NI Belova, NV Kuz'mina, NP
Citation
Gv. Girichev et al., Structure of the gas-phase sp- and d-element bis(dipivaloylmethanato) complexes, RUSS J C CH, 25(12), 1999, pp. 833-840
Citations number
43
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
12
Year of publication
1999
Pages
833 - 840
Database
ISI
SICI code
1070-3284(199912)25:12<833:SOTGSA>2.0.ZU;2-F
Abstract
The structures of coordination polyhedron MO4 and chelate core, the trends in changing the M-O bond length, the relationships between structural param eters, and electron-impact fragmentation routes are examined for the gas-ph ase sp- and d-element bis(dipivaloylmethanato) complexes M(C11O2H19)(2), wh ose metal atoms have the coordination number 4. The correlation between the se parameters and the electronic structure of the central atom is establish ed.