The ultrastructure of galactomannan/other polysaccharide (dextran and xanth
an) mixtures was studied by confocal laser scanning microscopy. Polysacchar
ides were covalently labelled with a fluorescent dye (RITC). Phase separati
on processes were observed, due to thermodynamic incompatibility between th
e two macromolecular species. The microscopic observations are compared to
rheological results and to the description of the macroscopic state of the
mixed systems.