DIASTEREOSELECTIVE PREPARATION OF CHIRAL-AT-METAL PENTAMETHYLCYCLOPENTADIENYL-IRIDIUM(III) AND PENTAMETHYLCYCLOPENTADIENYL-RHODIUM(III) COMPLEXES

Authors
LOZA ML PARR J SLAWIN AMZ
Citation
Ml. Loza et al., DIASTEREOSELECTIVE PREPARATION OF CHIRAL-AT-METAL PENTAMETHYLCYCLOPENTADIENYL-IRIDIUM(III) AND PENTAMETHYLCYCLOPENTADIENYL-RHODIUM(III) COMPLEXES, Polyhedron, 16(13), 1997, pp. 2321-2322
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
13
Year of publication
1997
Pages
2321 - 2322
Database
ISI
SICI code
0277-5387(1997)16:13<2321:DPOCP>2.0.ZU;2-D
Abstract
The reaction between the chiral bidentate Schiff base ligand (S)-N-sal icylidene-alpha-phenyethylamine (LH) and [CpMCl2](2) (M = Ir, Rh) in the presence of KOt-Bu yields in both cases diastereomerically pure (R )-CpM(L)Cl. (C) 1997 Elsevier Science Ltd.