METAL-COMPLEXES AS HOST MOLECULES - THE X-RAY CRYSTAL-STRUCTURE OF ,3-O-2-4-CH2(C6H13)C6H2)](4)CENTER-DOT-2CH(2)CL(2)

Authors
BERRIDGE TE CHEN HL HAMOR TA JONES CJ
Citation
Te. Berridge et al., METAL-COMPLEXES AS HOST MOLECULES - THE X-RAY CRYSTAL-STRUCTURE OF ,3-O-2-4-CH2(C6H13)C6H2)](4)CENTER-DOT-2CH(2)CL(2), Polyhedron, 16(13), 1997, pp. 2329-2333
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
13
Year of publication
1997
Pages
2329 - 2333
Database
ISI
SICI code
0277-5387(1997)16:13<2329:MAHM-T>2.0.ZU;2-S
Abstract
The reaction between [Mo(HBpz(3))(NO)I-2] and tetrahexylcalix[4]resorc inarene affords container molecules in which two, three or four {Mo(HB pz(3))(NO)} units are incorporated into the rim to produce a host site . A crystal structure of the tetrametallated derivative reveals that o ne nitrosyl ligand forms a hydrogen bond with a CH2Cl2 guest molecule included in the host site. (C) 1997 Elsevier Science Ltd.