REACTIONS OF PARTIALLY SOLVATED N-BUTYLMAGNESIUM CHLORIDE WITH DIISOPROPYL KETONE IN TOLUENE

Authors
TUULMETS A PALLIN V
Citation
A. Tuulmets et V. Pallin, REACTIONS OF PARTIALLY SOLVATED N-BUTYLMAGNESIUM CHLORIDE WITH DIISOPROPYL KETONE IN TOLUENE, Silicon, germanium, tin and lead compounds, 20(2), 1997, pp. 85-87
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
20
Issue
2
Year of publication
1997
Pages
85 - 87
Database
ISI
SICI code
0792-1241(1997)20:2<85:ROPSNC>2.0.ZU;2-N
Abstract
The ratios of yields of reduction and addition products for the title reaction were determined at different diethyl ether contents in the Gr ignard reagent, from zero addition up to the bisolvated reagent. The o btained dependence appeared to be unexpectedly complicated. Contrary t o the known effect of magnesium bromide addition, an enhanced magnesiu m chloride content in the reagent suppresses the addition reaction. Pa rtially solvated Grignard reagents can probably serve as tools for the investigation of specific solvent effects.