Ion-molecular reactions of free phenylium ions, generated by tritium beta-decay with bidentate arenes

Authors
Shchepina, NE Nefedov, VD Toropova, MA Avrorin, VV Lewis, SB Mattson, B
Citation
Ne. Shchepina et al., Ion-molecular reactions of free phenylium ions, generated by tritium beta-decay with bidentate arenes, TETRAHEDR L, 41(1), 2000, pp. 25-27
Citations number
27
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
1
Year of publication
2000
Pages
25 - 27
Database
ISI
SICI code
0040-4039(20000101)41:1<25:IROFPI>2.0.ZU;2-0
Abstract
Generation of free phenylium ions, obtained by tritium beta-decay and their ion-molecular reactions with bidentate arenes are described. The elaborate d nuclear-chemical method has been used for the synthesis of tritium labele d organic derivatives using halobenzenes. Two alternative pathways for inte raction of the phenylium ion with the bidentate arene, addition to the lone pair of the halogen or substitution on the aromatic ring, were revealed. ( C) 1999 Elsevier Science Ltd. All rights reserved.