Ne. Shchepina et al., Ion-molecular reactions of free phenylium ions, generated by tritium beta-decay with bidentate arenes, TETRAHEDR L, 41(1), 2000, pp. 25-27
Generation of free phenylium ions, obtained by tritium beta-decay and their
ion-molecular reactions with bidentate arenes are described. The elaborate
d nuclear-chemical method has been used for the synthesis of tritium labele
d organic derivatives using halobenzenes. Two alternative pathways for inte
raction of the phenylium ion with the bidentate arene, addition to the lone
pair of the halogen or substitution on the aromatic ring, were revealed. (
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