Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH

Authors
Muller, A Beugholt, C Koop, M Das, SK Schmidtmann, M Bogge, H
Citation
A. Muller et al., Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH, Z ANORG A C, 625(12), 1999, pp. 1960-1962
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
12
Year of publication
1999
Pages
1960 - 1962
Database
ISI
SICI code
0044-2313(199912)625:12<1960:FAOSAS>2.0.ZU;2-7
Abstract
The syntheses and structures of the two mixed-valence crystalline molybdenu m blue compounds Na-26[Mo142O432(H2O)(58)H-14] ca. 300H(2)O (1) (containing the maximal number of well defined defects which influence the overall str ucture and the reactivity of the anionic cluster) and Na-16[(MoO3)(176)(H2O )(63)(CH3OH)(17)H-16].ca. 600H(2)O ca. 6 CH3OH (2) (obtained in an optimize d high-yield synthesis) are reported with reference to the critical conditi ons required for the isolation of corresponding crystalline materials.