The SCN- ion as an ambidentate ligand - Synthesis and crystal structures of (Bu4N)(4)[Ag2Fe2(SCN)(12)] and (Et4N)(2) (1)(infinity)[Ag2Fe(SCN)(6)]

Authors
Krautscheid, H Gerber, S
Citation
H. Krautscheid et S. Gerber, The SCN- ion as an ambidentate ligand - Synthesis and crystal structures of (Bu4N)(4)[Ag2Fe2(SCN)(12)] and (Et4N)(2) (1)(infinity)[Ag2Fe(SCN)(6)], Z ANORG A C, 625(12), 1999, pp. 2041-2044
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
12
Year of publication
1999
Pages
2041 - 2044
Database
ISI
SICI code
0044-2313(199912)625:12<2041:TSIAAA>2.0.ZU;2-R
Abstract
In (Bu4N)(4)[Ag2Fe2(SCN)(12)] . 2CH(3)NO(2) (1) and (Et4N)(2)[Ag2Fe(SCN)(6) ] (2) the ambidentate SCN- anions link Ag+ with Fe3+ and Fe2+ centers, resp ectively. The tetranuclear anions in 1 are built from [Fe(NCS)(6)](3-) grou ps connected by Ag+ ions. In 2 the same bridging pattern leads to polymeric anionic chains containing [Fe(NCS)(6)](4-) groups linked by Ag+- ions. (Bu4N)(4)[Ag2Fe2(SCN)(12)] . 2 CH3NO2 (1): a = 1184.10(10), b = 1370.80(10) , c = 1776.5(2) pm, alpha = 99.090(10), beta = 192.100(10), gamma = 100.360 (10)degrees, V = 2715.5(4) . 10(6) pm(3), space group P (1) over bar; (Et4N)(2)[Ag2Fe(SCN)(6)] (2): a = 1607.0(2), b = 1006.92(9), c =1096.13(9) pm, V = 1773.7(3) . 10(6) pm(3), space group Pnnm.