Estimation of transport properties of liquids

Citation
Mr. Riazi et al., Estimation of transport properties of liquids, CHEM ENG CO, 176, 1999, pp. 175-193
Citations number
21
Categorie Soggetti
Chemical Engineering
Journal title
CHEMICAL ENGINEERING COMMUNICATIONS
ISSN journal
00986445 → ACNP
Volume
176
Year of publication
1999
Pages
175 - 193
Database
ISI
SICI code
0098-6445(1999)176:<175:EOTPOL>2.0.ZU;2-2
Abstract
Based on the theory of intermolecular forces and the Hildebrand relation, a generalized equation in terms of refractive index is proposed to estimate viscosity, thermal conductivity and diffusion coefficients of liquid non-po lar compounds at various temperatures. Analytical equations are provided to estimate transport properties of n-alkanes in terms of molecular weight. A verage deviations for all three properties of various hydrocarbons from C-5 to C-20 are within 1% for a large number of data points. The proposed equa tion also predicts transport properties of some polar compounds with a reas onable degree of accuracy.