Thin graded hetero-epitaxial AlGaAs layer has been grown from the undersatu
rated Liquid Phase Epitaxial (LPE) technique. The grown layers have been ch
aracterized using Laser Raman scattering studies. The peak position and int
ensity ratio of GaAs and AlAs like LO phonon frequencies have been measured
and compared with conventional LPE grown AlGaAs epitaxial layer. The behav
iour of GaAs and AlAs like LO phonons has been found to vary with the alumi
num composition in the grown layer. Raman peak positions have been observed
to shift to lower wavenumber in GaAs like LO phonon and higher wavenumber
side of AlAs like LO phonon. Aluminum free features have been noticed in IE
E grown AlGaAs (x > 0.8) hetero epitaxial layers.