Citation
Sss. Raj et al., Crystal structure of 2,2-(benzenesulphonyl)-1-(4-chlorobenzoyl) cyclopropane, CRYST RES T, 34(10), 1999, pp. 1333-1337
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300
→ ACNP
Volume
34
Issue
10
Year of publication
1999
Pages
1333 - 1337
Database
ISI
SICI code
0232-1300(1999)34:10<1333:CSO2C>2.0.ZU;2-0
Abstract
The title compound (C22H17O5S2Cl) crystallizes in the monoclinic space grou
p P2(1)/c with cell constants a = 10.511(2), b = 15.452(1), c = 13.025(2) A
ngstrom, beta = 103.70(2)degrees, V = 2055.3(5)Angstrom(3), Z=4, D-cal=1.49
Mgm(-3) and T=293K. The structure was solved by direct methods and refined
by full-matrix least-squares procedure using 3876 reflections to a final R=
0.0526 and wR=0.1787. One of the benzenesulphonyl group is trans and the ot
her is cis to cyclopropane ring. The structure is stabilized by van der Waa
l's type of interactions.