Free thermal convection and mixed convection are considered as potential me
chanisms for mass and heat transport in sedimentary basins. Mixed conventio
n occurs when horizontal flows (forced convection) are superimposed on ther
mally driven flows. In cross section, mixed convection is characterized by
convection cells that migrate laterally in the direction of forced convecti
ve flow. Two-dimensional finite-element simulations of variable-density gro
undwater flow and heat transport in a horizontal porous layer were performe
d to determine critical mean Rayleigh numbers for the onset of free convect
ion, using both isothermal and semi-conductive boundaries. Additional simul
ations imposed a varying lateral fluid flux on the free-convection pattern.
Results from these experiments indicate that forced convection becomes dom
inant, completely eliminating buoyancy-driven circulation, when the total f
orced-convection fluid flux exceeds the total flux possible due to free con
vection. Calculations of the thermal rock alteration index (RAI=q.del T) de
lineate the patterns of potential diagenesis produced by fluid movement thr
ough temperature gradients. Free convection produces a distinct pattern of
alternating positive and negative RAIs, whereas mixed convection produces a
simpler layering of positive and negative values and in general less diage
netic alteration.