A simple analytical expression to determine cell potential (E) against curr
ent density (i) behaviour in polymer electrolyte fuel cells (PEFCs) was der
ived. The equation describes experimental data over the whole range of curr
ent density taking into account possible mass transport limitations. The em
pirical equation was used to fit experimental data obtained in a 50 cm(2) s
ingle cell in H-2/air operation using electrodes with low Pt loading (simil
ar to 0.1 mg cm(-2)). A good agreement between theoretical and experimental
data was found.