Laser ablated samples of poly(ether imide) were analyzed by XPS-imaging and
by small area X-ray photoelectron spectroscopy (XPS). XPS-imaging was capa
ble of detecting concentration variations of the order of 1.5% and revealed
a relatively homogeneous deposition of carbon soot around the laser-ablate
d hole. A clear modification of the poly(ether imide) by the laser irradiat
ion was determined within the laser-ablated hole by small area XPS. While t
he relative carbon content of the polymer was increased, the nitrogen and o
xygen content was reduced. (C) 1999 Elsevier Science B.V. All rights reserv
ed.