X-ray and UV photoelectron spectroscopies were used to measure the valence
band discontinuity at the interface between (0001) 2H-GaN films and 3C-SiC
(111) substrates. For GaN films grown by NH3 gas source molecular beam epit
axy on (1 x 1) 3C-SiC on-axis surfaces, a type I band alignment was observe
d with a valence band discontinuity of 0.5 +/- 0.1 eV. A type I band alignm
ent was also determined for GaN films grown on (3 x 3) 3C-SiC, hut with a l
arger valence band discontinuity of 0.8 +/- 0.1 eV.