Ws. Wong et al., Integration of GaN thin films with dissimilar substrate materials by Pd-Inmetal bonding and laser lift-off, J ELEC MAT, 28(12), 1999, pp. 1409-1413
Gallium nitride (GaN) thin films grown on sapphire substrates were successf
ully bonded and transferred onto GaAs, Si, and polymer "receptor" substrate
s using a low-temperature Pd-In bond followed by a laser lift-off (LLO) pro
cess to remove the sapphire growth substrate. The GaN/sapphire structures w
ere joined to the receptor substrate by pressure bonding a Pd-In bilayer co
ated GaN surface onto a Pd coated receptor substrate at a temperature of 20
0 degrees C. X-ray diffraction showed that the intermetallic compound PdIn3
had formed during the bonding process. LLO, using a single 600 mJ/cm(2), 3
8 ns KrF (248 nm) excimer laser pulse directed through the transparent sapp
hire substrate, followed by a low-temperature heat treatment, completed the
transfer of the GaN onto the "receptor" substrate. Cross-sectional scannin
g electron microscopy and x-ray rocking curves showed that the film quality
did not degrade significantly during the bonding and LLO process.