The linear compressibilities and the thermal expansion of an untwinned, nea
rly optimal doped YBa2Cu3O6.94 single crystal were measured along the three
crystallographic axes with a high-resolution dilatometer mounted in a high
-pressure cell. The measurements were performed in a temperature range from
50 K to 320 K under hydrostatic gas pressure of maximal 0.65 GPa. At a tem
perature of 300 K the measured bulk modulus is reduced and shows a very str
ong enhancement under increasing pressure due to pressure-induced oxygen or
dering. This ordering process can also be related to a glass transition see
n in the thermal expansion above 225 K. At lower temperatures, when oxygen
ordering is frozen, the bulk modulus is increased and shows a significantly
reduced enhancement under pressure. This pressure dependence, however, is
still anomalous high, probably caused by bonds of extremely different compr
essibilities within the unit cell. The widely spread literature data of the
bulk modulus can be explained by this high pressure dependence.