Morphology, conductivity, and mechanical properties of polypyrrole-containing composites

Citation
J. Pionteck et al., Morphology, conductivity, and mechanical properties of polypyrrole-containing composites, J MACR S PH, B38(5-6), 1999, pp. 737-748
Citations number
6
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS
ISSN journal
00222348 → ACNP
Volume
B38
Issue
5-6
Year of publication
1999
Pages
737 - 748
Database
ISI
SICI code
0022-2348(1999)B38:5-6<737:MCAMPO>2.0.ZU;2-F
Abstract
An electrical-conducting polypropylene/polypyrrole (PP/PPY) composite was p repared by the chemically oxidative modification reaction of pyrrole on the surface of PP particles in suspension. Another type of PP/PPy composite wa s prepared by mixing the coated PP particles with noncoated PP particles at room temperature. The composites were processed by compression molding or by injection molding. The injection-molded composites exhibited better mech anical properties compared to compression-molded samples, while these compo sites showed better antistatic behavior and electrical conductivity. The di fferences in the behavior of the two types of composites were caused by the different structure of the PPy phase, which was studied by hot-stage optic al microscopy and X-ray photoelectron spectroscopy (XPS).