An electrical-conducting polypropylene/polypyrrole (PP/PPY) composite was p
repared by the chemically oxidative modification reaction of pyrrole on the
surface of PP particles in suspension. Another type of PP/PPy composite wa
s prepared by mixing the coated PP particles with noncoated PP particles at
room temperature. The composites were processed by compression molding or
by injection molding. The injection-molded composites exhibited better mech
anical properties compared to compression-molded samples, while these compo
sites showed better antistatic behavior and electrical conductivity. The di
fferences in the behavior of the two types of composites were caused by the
different structure of the PPy phase, which was studied by hot-stage optic
al microscopy and X-ray photoelectron spectroscopy (XPS).