The paper brings a brief survey of the direct chemical methods for preparat
ion of polypropylene (PP) derivatives, using mostly peroxides, UV or gamma
irradiation and, in some cases, also strong acidic reagents for formation o
f precursors of binding the functional groups or side chains on the PP back
bone. By this means, sulfonated, chlorinated, carboxylated, hydroperoxidate
d PP as the examples of functionalized PP's, can be prepared. As examples o
f binding side chains to the PP, the grafting of PP with unsaturated monome
rs like styrene, methyl methacrylate, acrylates, maleic anhydride, and its
derivatives are described. The application of PP derivatives and their impo
rtance in preparation of polymer blends and composites is illustrated.