Polypropylene derivatives

Authors
Citation
E. Borsig, Polypropylene derivatives, J MACR S PU, A36(11), 1999, pp. 1699-1715
Citations number
45
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
ISSN journal
10601325 → ACNP
Volume
A36
Issue
11
Year of publication
1999
Pages
1699 - 1715
Database
ISI
SICI code
1060-1325(1999)A36:11<1699:PD>2.0.ZU;2-G
Abstract
The paper brings a brief survey of the direct chemical methods for preparat ion of polypropylene (PP) derivatives, using mostly peroxides, UV or gamma irradiation and, in some cases, also strong acidic reagents for formation o f precursors of binding the functional groups or side chains on the PP back bone. By this means, sulfonated, chlorinated, carboxylated, hydroperoxidate d PP as the examples of functionalized PP's, can be prepared. As examples o f binding side chains to the PP, the grafting of PP with unsaturated monome rs like styrene, methyl methacrylate, acrylates, maleic anhydride, and its derivatives are described. The application of PP derivatives and their impo rtance in preparation of polymer blends and composites is illustrated.