Thermodynamic parameters for the solvation of monatomic ions in water

Authors
Fawcett, WR
Citation
Wr. Fawcett, Thermodynamic parameters for the solvation of monatomic ions in water, J PHYS CH B, 103(50), 1999, pp. 11181-11185
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
103
Issue
50
Year of publication
1999
Pages
11181 - 11185
Database
ISI
SICI code
1520-6106(199912)103:50<11181:TPFTSO>2.0.ZU;2-Y
Abstract
The estimation of solvation parameters for monatomic ions is reviewed and n ew values for the Gibbs energy, enthalpy, and entropy of solvation are give n on the basis of the most recent thermodynamic data. The results for alkal i metal and alkaline earth metal cations, and for the halide anions togethe r with the sulfide anion, are examined within the context of a model based on the mean spherical approximation (MSA) for the Gibbs energy of ion-solve nt interactions.