C. Popescu et al., On the validity of the steady-state approximation in non-isothermal kinetics - Part IV. The case of constant rate thermal analysis, J THERM ANA, 58(3), 1999, pp. 677-681
The paper investigates the validity of steady-state approximation for the c
ase of constant rate thermal analysis experiments. It is shown that the app
roximation holds for the experiments run with a controlled rate of either t
he decomposition of the compound, or the production of gas.