Titration calorimetric investigations on the interactions of Zn(II) porphyrin complexes with pyridine in benzene and chloroform at 298.15 k

Citation
W. Zielenkiewicz et al., Titration calorimetric investigations on the interactions of Zn(II) porphyrin complexes with pyridine in benzene and chloroform at 298.15 k, J THERM ANA, 58(3), 1999, pp. 741-748
Citations number
13
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
58
Issue
3
Year of publication
1999
Pages
741 - 748
Database
ISI
SICI code
1388-6150(199912)58:3<741:TCIOTI>2.0.ZU;2-3
Abstract
Titration calorimetry was used in a thermodynamic study on the interactions of pyridine with natural zinc(II) porphyrin derivatives in benzene and chl oroform at 298.15 K. The ability of zinc porphyrins to coordinate to pyridi ne is higher in benzene than in chloroform and also depends on the molecula r structure of the metalloporphyrin.