A close-packed one-dimensional array of gold nanoparticles was prepared wit
h DNA as a rigid anionic polymer template. Gold nanoparticles with dense po
sitive charges were prepared by modifying with dialkylammonium-disulfide. T
hese cationic gold nanoparticles were adsorbed effectively on anionic DNA m
olecules. Electron microscopy indicated that the particle array had a close
-packed structure with a small inter-particle distance. The formation mecha
nism of the close packing is discussed.