Enantioselective recognition of a pair of novel receptors for amino acid zwitterions

Authors
Lu, GY Liu, F Song, W He, WJ Prados, P de Mendoza, J
Citation
Gy. Lu et al., Enantioselective recognition of a pair of novel receptors for amino acid zwitterions, MAT SCI E C, 10(1-2), 1999, pp. 29-32
Citations number
8
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS
ISSN journal
09284931 → ACNP
Volume
10
Issue
1-2
Year of publication
1999
Pages
29 - 32
Database
ISI
SICI code
0928-4931(199912)10:1-2<29:EROAPO>2.0.ZU;2-D
Abstract
A pair of artificial enantiotopic receptors la, Ib composed of (S,S) or (R, R) chiral bicyclic guanidinium, azacrown ether and (t-butyldiphenylsilyloxy )methyl group for amino acid zwitterions have been synthesized. The liquid- liquid competition extraction experiments and H-1 NMR studies indicate that the receptor la with (S,S) configuration and Ib with (R,R) configuration s electively recognize L- and D-aromatic amino acids, respectively. (C) 1999 Elsevier Science S.A. All rights reserved.