M. Koetse et al., Films grown from polyamines and reactive dyes by alternating polyelectrolyte adsorption/surface activation (CoMPAS), MAT SCI E C, 10(1-2), 1999, pp. 107-113
Coatings by multiple polyelectrolyte adsorption/surface activation (CoMPAS)
is a new method to form thin polymer films by alternating the physisorptio
n of polyelectrolytes with a surface activation process using oppositely ch
arged reagents. Here, we show that CoMPAS is also applicable for simple pol
yamines and reactive dyes. The amines serve simultaneously as cationic cent
ers for adsorption and as reactive groups for the dyes. Film growth is line
ar according to UV-Vis spectroscopy and ellipsometry. Second harmonic gener
ation (SHG) experiments were performed to study the ordering of the chromop
hores in the films. (C) 1999 Elsevier Science S.A. All rights reserved.