We show that a deep level, the ES1, introduced in n-GaN by sputter-depositi
on of gold Schottky contacts exhibits metastable-like behaviour during temp
erature cycling between 55 and 250 K. The ES1 has an energy level 0.22 +/-
0.02 eV below the conduction band. We provide some evidence that indicates
that the defect responsible for the ES1 has a second energy level, the ES1*
, and that the metastable behaviour of the ES1 may be due to negative-U ord
ering of these two energy levels. Furthermore, held effect measurements ind
icate that the ES1 level has a donor character, while the ES1* level is pro
bably an acceptor. (C) 1999 Elsevier Science B.V. All rights reserved.