We show that the detailed atomic structure of vacancy-impurity complexes in
Si can be experimentally determined by combining positron lifetime and ele
ctron momentum distribution measurements. The vacancies complexed with a si
ngle impurity, V-P and V-As, are identified in electron irradiated Si. The
formation of native vacancy defects is observed in highly As-doped Si at th
e doping level of 10(20) cm(-3). The defects are identified as monovacancie
s surrounded by three As atoms. The formation of V-As-3 complex is consiste
nt with the theoretical descriptions of As diffusion and electrical deactiv
ation in highly As doped Si. (C) 1999 Elsevier Science B.V. All rights rese
rved.