We have investigated the strong anisotropic polarization of the prominent Y
line luminescence at 2.62 eV in thin ZnSe layers grown by molecular beam e
pitaxy on (001)-oriented GaAs substrates. For thin ZnSe films a pronounced
anisotropic polarization collinearly to the [ (1) over bar 10] crystallogra
phic direction with intensity ratios up to 1:8 for polarizer orientations p
arallel and perpendicular to [101] is found. In this samples the matrix lum
inescence shows no preferential orientation of the electric field vector in
the plane perpendicular to the axis of growth. For ZnSe films with a layer
thickness just below the critical thickness we observed a fine structure o
f up to nine subcomponents in the Y line spectrum. We interpret the Y line
as a radiative recombination of an exciton bound to a 60 degrees alpha-disl
ocation, which is dissociated into a 900 and 30 degrees Shockley partial di
slocation bounding a stacking fault ribbon. We relate the fine structure to
a discrete set of the stacking fault distances. (C) 1999 Elsevier Science
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