Oxidation of 1-alkylcycloalkanols with Pb-IV and Mn-III compounds under mechanical activation

Authors
Kapustina, NI Sokova, LL Makhaev, VD Petrova, LA Nikishin, GI
Citation
Ni. Kapustina et al., Oxidation of 1-alkylcycloalkanols with Pb-IV and Mn-III compounds under mechanical activation, RUSS CHEM B, 48(11), 1999, pp. 2080-2082
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
11
Year of publication
1999
Pages
2080 - 2082
Database
ISI
SICI code
1066-5285(199911)48:11<2080:OO1WPA>2.0.ZU;2-T
Abstract
A mechanoactivated solid-state oxidative decyclization of 1-alkylcycloalkan ols under the action of the Pb(OAc)(4)-MX or Mn(OAc)(3)-MX systems (MX is a metal halide) was carried out for the first time. The reaction affords exc lusively omega-haloalkanones.