Complexation of platinum in sorption of tetrachloroplatinate(II) ion by fibrous sorbent based on polyakrylonitrile modified with thiosemicarbazide

Authors
Simanova, SA Kuznetsova, TV Belyaev, AN Knyaz'kov, OV Konovalov, LV
Citation
Sa. Simanova et al., Complexation of platinum in sorption of tetrachloroplatinate(II) ion by fibrous sorbent based on polyakrylonitrile modified with thiosemicarbazide, RUS J AP CH, 72(8), 1999, pp. 1344-1350
Citations number
38
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
72
Issue
8
Year of publication
1999
Pages
1344 - 1350
Database
ISI
SICI code
1070-4272(199908)72:8<1344:COPISO>2.0.ZU;2-8
Abstract
Sorption properties of a fibrous sorbent based on polyakrylonitrile modifie d with thiosemicarbazide (GLIPAN-1) were studied with respect Co platinum(I I) chlorocomplex K-2[PtCl4]. Kinetic and capacity characteristics of the so rbent were determined in hydrochloric-acid and chloride solutions. A probab le mechanism of sorption of platinum(II) chlorocomplex was established, and the composition of compounds formed, in the fiber phase was determined.