Features of dimethylacrylamide polymerization under the action of tris-pi-allylchromium

Authors
Shibaev, LA Fedorova, LA Antonova, TA Klenin, SI Erusalimskii, BL Novakov, PP Kukling, D Adler, HJP
Citation
La. Shibaev et al., Features of dimethylacrylamide polymerization under the action of tris-pi-allylchromium, RUS J AP CH, 72(8), 1999, pp. 1427-1432
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
72
Issue
8
Year of publication
1999
Pages
1427 - 1432
Database
ISI
SICI code
1070-4272(199908)72:8<1427:FODPUT>2.0.ZU;2-I
Abstract
Polymerization of N,N-dimethylacrylamide and tert-butyl acrylate under the action of tris-pi-allylchromium was studied by mass-spectrometric thermal a nalysis. Polymerization yields branched and crosslinked macromolecules; the ir structure is determined by the presence of two types of active centers i n the molecules of the growing polymer.