Theoretical conformational analysis of phosphine oxides

Authors
Ishmaeva, EA Kataev, VE Bazhanova, ZG Vereshchagina, YA Kataev, AV
Citation
Ea. Ishmaeva et al., Theoretical conformational analysis of phosphine oxides, RUSS J G CH, 69(7), 1999, pp. 1115-1119
Citations number
18
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
7
Year of publication
1999
Pages
1115 - 1119
Database
ISI
SICI code
1070-3632(199907)69:7<1115:TCAOPO>2.0.ZU;2-E
Abstract
Theoretical conformational analysis (PM3) of a series of phosphine oxides R 2P(O)CH2X showed that the population of the form with the P=O bond trans to C-X tends to decrease with increasing size of substituents at the phosphor us atom and in the methylene group.