Structure and intramolecular lability of N-(thio)phosphoryl(thio)amides: VI. H-1, C-13, and P-31 NMR interpretation of the phosphorylotropic rearrangement in the N,N '-bis(diisopropoxythiophosphorylaminocarbonyl)-1,10-diaza-18-crown-6 ether in DMSO solution

Authors
Karataeva, FK
Citation
Fk. Karataeva, Structure and intramolecular lability of N-(thio)phosphoryl(thio)amides: VI. H-1, C-13, and P-31 NMR interpretation of the phosphorylotropic rearrangement in the N,N '-bis(diisopropoxythiophosphorylaminocarbonyl)-1,10-diaza-18-crown-6 ether in DMSO solution, RUSS J G CH, 69(7), 1999, pp. 1139-1143
Citations number
8
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
7
Year of publication
1999
Pages
1139 - 1143
Database
ISI
SICI code
1070-3632(199907)69:7<1139:SAILON>2.0.ZU;2-G
Abstract
The phosphorylotropic rearrangement in the N,N'-bis(diisopropoxythiophospho rylaminocarbonyl)-1,10-diaza-18-crown-6 ether in DMSO solution was studied by H-1,C-13, and P-31 NMR spectroscopy. The transition from the amide to ph osphorylotropic form is accompanied by simultaneous transformation of signa ls of all structural elements in the H-1, C-13, and P-31 NMR spectra.