The electrodialysis (ED) process using ion-exchange membranes is mainly use
d for the desalination of brackish water and wheys and for the concentratio
n of seawater. ED has of late become a unique operation for the separation
of chemicals from a mixture of ionic and nonionic substances. During the ma
nufacture of pentaerythritol, sodium formate is also formed, which is to be
separated from the mixture. Since ED is used to separate electrolytes from
nonelectrolytes, attempts were made to make use of this process for the se
paration of sodium formate and pentaerythritol from their mixture. In this
paper we have discussed the experimental results obtained their separation
under different experimental conditions.