T. Jonsson et al., ENERGY BARRIER DISTRIBUTION OF A NONINTERACTING NANO-SIZED MAGNETIC PARTICLE SYSTEM, Journal of magnetism and magnetic materials, 168(3), 1997, pp. 269-277
AC-susceptibility and magnetic relaxation data are analysed to determi
ne the distribution of energy barriers (E-b) of an assembly of small m
agnetic particles. The assembly, a dilute frozen ferrofluid, consists
of spherical nano-sized maghemite (gamma-Fe2O3) particles with a media
n diameter of 70 Angstrom. Assuming a direct proportionality between E
-b and particle volume, the volume distribution is found to be describ
ed by a normalised gamma distribution. The system is not adequately de
scribed by the commonly adopted log-normal distribution function, whic
h comparably should yield an excess amount of large particles sizes. F
rom the analyses, accurate values of the Arrhenius law prefactor (tau(
0) = 4 x 10(-10) s) and the magnetic anisotropy constant are derived.