Single crystals of K2SeO4. Te(OH)(6), (KTSe) were obtained by slow evaporat
ion at 300 K. The differential scanning calorimetry diagram showed three an
omalies at 433, 480 and 495 K, respectively. The dielectric constant evolut
ion as a function of frequency and temperature revealed the first two anoma
lies. The peak at 433 K was attributed to the ferroelectric-paraelectric ph
ase transition and the second one to the superionic phase transition. X-ray
powder diffraction data confirmed that the third anomaly at 495 K characte
rizes the decomposition before melting of the material. (C) 2000 Elsevier S
cience BN. All rights reserved.