Copper(II)-8-mercaptoquinoline, copper(II)-5,8-dimercaptoquinoline and copper(II)-5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized matrix

Citation
Ov. Mikhailov et al., Copper(II)-8-mercaptoquinoline, copper(II)-5,8-dimercaptoquinoline and copper(II)-5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized matrix, TRANSIT MET, 25(1), 2000, pp. 45-51
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
25
Issue
1
Year of publication
2000
Pages
45 - 51
Database
ISI
SICI code
0340-4285(200002)25:1<45:CCAC>2.0.ZU;2-O
Abstract
Novel complexing processes in the Cu-II-8-mercaptoquinoline, Cu-II-5,8-dime rcaptoquinoline and Cu-II-5-thiomethyl-8-mercaptoquinoline systems proceedi ng in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in cont act with aqueous solutions of the ligands indicated, have been studied. Und er the conditions specified for complexing in the Cu-II-8-mercaptoquinoline system, only a monomeric water-insoluble coordination compound was formed. In the Cu-II-5,8-dimercaptoquinoline system, three coordination compounds were formed and, in the Cu-II-5-thiomethyl-8-mercaptoquinoline system, two such compounds were formed. Conversely, complexing in solution or solid pha se results in the formation only coordination compounds in each of the syst em studied.