Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate

Authors
Cavalheiro, ETG Ionashiro, M Marino, G Breviglieri, ST Chierice, GO
Citation
Etg. Cavalheiro et al., Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate, TRANSIT MET, 25(1), 2000, pp. 69-72
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
25
Issue
1
Year of publication
2000
Pages
69 - 72
Database
ISI
SICI code
0340-4285(200002)25:1<69:CBISAT>2.0.ZU;2-C
Abstract
The thermal decomposition of pyrrolidinedithiocarbamate and piperidinedithi ocarbamate complexes of Co-II, Ni-II, Cu-II and Hg-II have been studied by thermogravimetry and differential scanning calorimetry. The decomposition i ntermediates and final products were identified by their X-ray diffraction patterns. The i.r. spectra are discussed in terms of the thermal decomposit ion pathways.