Copper(II) complexes of 2-pyridineformamide N(4)-methylthiosemicarbazone

Authors
West, DX Swearingen, JK El-Sawaf, AK
Citation
Dx. West et al., Copper(II) complexes of 2-pyridineformamide N(4)-methylthiosemicarbazone, TRANSIT MET, 25(1), 2000, pp. 80-83
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
25
Issue
1
Year of publication
2000
Pages
80 - 83
Database
ISI
SICI code
0340-4285(200002)25:1<80:CCO2N>2.0.ZU;2-A
Abstract
Reduction of 2-cyanopyridine by sodium in dry MeOH in the presence of N(4)- methylthiosemicarbazide produces 2-pyridineformamide N(4)-methylthiosemicar bazone, HAm4M. Copper(II) complexes have been prepared and characterized by molar conductivities, magnetic susceptibilities and spectroscopic techniqu es. Coordination is via the pyridyl nitrogen, imine nitrogen and thione or thiolato sulfur, when coordinating as the neutral or anionic ligand, respec tively.