V. Cannizzaro et al., Determination of cobalt and iron in estuarine and coastal waters using flow injection with chemiluminescence detection, ANALYST, 125(1), 1999, pp. 51-57
Flow injection with chemiluminescence detection (FI-CL) was used to determi
ne cobalt and iron in estuarine and coastal waters. Cobalt(II) was determin
ed by means of a pyrogallol-hydrogen peroxide-sodium hydroxide reaction in
the presence of methanol and the surfactant cetyltrimethylammonium bromide
(CTAB). With pyrogallol, the sensitivity was enhanced compared with the tra
ditional reagent, gallic acid. The practical limit of detection in sea-wate
r was 5 pM (3s) and there was good agreement with certified values for the
sea-water CRMs NASS-5 (0.16 +/- 0.01 nM), CASS-3 (0.60 +/- 0.09 nM) and SLE
W-2 (0.93 +/- 0.13 nM). Results for an Irish Sea sample gave good agreement
with data obtained using cathodic stripping voltammetry. Iron(II + III) wa
s determined using a luminol reaction with dissolved oxygen as the oxidant.
The practical limit of detection was 40 pM (3s) and results from shipboard
analysis of the CRM NASS-4 (1.95 +/- 0.14 nM) were in good agreement with
the certified value (1.88 +/- 0.29 nM). Field evaluation of the instrumenta
tion and analytical methods was achieved through a series of local surveys
in the Tamar Estuary (UK), from which environmental data are presented.