G. Centi et al., Catalytic wet oxidation with H2O2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts, CATAL TODAY, 55(1-2), 2000, pp. 61-69
The catalytic wet oxidation with hydrogen peroxide (WHPO) of diluted formic
, acetic and propionic acid solutions (total organic carbon of 30 mg C/l) i
n the 25-70 degrees C temperature range using a Fe3+-containing zeolite (Fe
/ZSM5) is compared with the behavior of homogeneous Fe3+ catalysts at the s
ame experimental conditions. Although the heterogeneous catalysts have a hi
gher reactivity and a reduced dependence on the pH of the solution in compa
rison to the homogeneous Fe3+ catalysts, they also have a higher rate of th
e side reaction of hydrogen peroxide decomposition to water and oxygen. Lea
ching tests indicate that the activity of the heterogeneous catalyst is not
due to leached iron ions, although a small amount of iron was found in the
aqueous solution. It was also observed that catalytic behavior could be re
produced in consecutive catalytic experiments, but an intermediate calcinat
ion step is necessary to oxidize the organic species which remain trapped i
nside the pore of the zeolite. (C)2000 Elsevier Science B.V. All rights res
erved.