Numerical hydrodynamic simulations of the growth and collapse of a 10
mu m air bubble in water were performed. Both the air and the water ar
e treated as compressible fluids. The calculations show that the colla
pse is nearly isentropic until the final 10 ns, after which a strong s
pherically converging shock wave evolves and creates enormous temperat
ures and pressures in the inner 0.02 mu m of the bubble. The reflectio
n of the shock from the center of the bubble produces a diverging shoc
k wave that quenches the high temperatures (>30 eV) and pressures in l
ess than 10 ps (full width at half maximum). The picosecond pulse widt
hs are due primarily to spherical convergence/divergence and nonlinear
stiffening of the air equation of state that occurs at high pressures
. The results are consistent with recent measurements of sonoluminesce
nce that had optical pulse widths less than 50 ps and 30 mW peak radia
ted power in the visible.