Citation
T. Kochi et al., Rh4S7 and Ir3CuS6 clusters with di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes, CHEM LETT, (12), 1999, pp. 1279-1280
Citations number
32
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022
→ ACNP
Issue
12
Year of publication
1999
Pages
1279 - 1280
Database
ISI
SICI code
0366-7022(199912):12<1279:RAICWD>2.0.ZU;2-2
Abstract
Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp*MCl(mu-SH)
(2)MClCp*] (M = Rh, Ir) with CuCl2. 2H(2)O lead to formation of Rh4S7 and I
r3CuS6 clusters [(Cp*Rh)(4)(mu(3)-S-2)(2)(mu(4)-S-3)][CuCl2](2) and [(Cp*Ir
)(3)(mu(3)-S-2)(3)(CuCl2)][CuCl2] through the oxidative S-S bond formation,
the former of which contains a trisulfido ligand of the unprecedented mu(4
)-eta(2):eta(1):eta(1):eta(1) coordination mode.