A new process for C-Si bond formation from cis-alkyl(silyl)platinum(II) complexes

Authors
Ozawa, F Kitaguchi, M Katayama, H
Citation
F. Ozawa et al., A new process for C-Si bond formation from cis-alkyl(silyl)platinum(II) complexes, CHEM LETT, (12), 1999, pp. 1289-1290
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
12
Year of publication
1999
Pages
1289 - 1290
Database
ISI
SICI code
0366-7022(199912):12<1289:ANPFCB>2.0.ZU;2-O
Abstract
The complexes cis-PtR(SiHPh2)(PMe2Ph)(2) (R = Me, Et, Pr, Bu) have been fou nd to undergo two types of C-Si bond formation process. One is a novel reac tion process via isomerization to cis-PtH(SiRPh2)(PMe2Ph)(2), and the other is C-Si reductive elimination involving prior displacement of a PMe2Ph lig and with diphenylacetylene added to the system.